网站首页    
学院新闻
学生工作
通知公告
学术报告
学术前沿
党员之家
先锋行动
学术动态
飘窗新闻


当前位置: 网站首页 学术动态 正文
褚雪强、沈志良团队在Org. Lett.发表论文
阅读次数: 添加时间:2022/03/14 发布:

Nickel-catalyzed direct cross-coupling of aryl sulfonium salt with aryl bromide

Na-Na Ma, Jing-Ao Ren, Xiang Liu, Xue-Qiang Chu, Weidong Rao, and Zhi-Liang Shen*,†

Technical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China. E-mail: ias_zlshen@njtech.edu.cn.

Jiangsu Provincial Key Lab for the Chemistry and Utilization of Agro-Forest Biomass, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China.

 

Abstract: The direct cross-couplings of aryl sulfonium salts with aryl halides could be achieved by using nickel as reaction catalyst. The reactions proceeded efficiently via C-S bond activation in the presence of magnesium turnings and lithium chloride in THF at ambient temperature to afford the corresponding biaryls in moderate to good yields, potentially serving as an attractive alternative to conventional cross-coupling reactions employing pre-prepared organometallic reagents.

 

Org. Lett. 2022, doi: 10.1021/acs.orglett.2c00357. (Impact factor: 6.005)

论文链接:

地址:南京浦口区浦珠南路30号 邮编:211880 电话:025-58139535、9536、9537 邮箱:chem@njtech.edu.cn

Copyright © 2019 欧宝体育官方登录入口 All Rights Reserved.

总共访问: 今日访问:  
 

欧宝体育官方登录入口|「首页进入」