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褚雪强
阅读次数: 添加时间:2021/03/29 发布:

褚雪强 博士

欧宝体育官方登录入口 化学与分子工程(IAS

Email: xueqiangchu@njtech.edu.cn

ORCID: 0000-0002-9173-1508; Researcher ID: T-3254-2018

 

个人简历:

(3) 2017-7至今,欧宝体育官方登录入口,先进化学制造研究院,助理教授

(2) 2012-92017-6,苏州大学,有机化学,博士,导师:纪顺俊教授

(1) 2008-92012-6,苏州大学,化学类,学士,导师:纪顺俊教授

 

研究方向:

多重C-F键官能化、自由基反应、含氟杂环化合物合成、绿色化学

 

研究成果

在多重C-F键官能化反应研究方面,取得了具有重要影响力的原创性研究成果。先后在国内外有影响的学术刊物,如Chem, iScience, ACS Catalysis, Organic Letters, Green Chemistry, Chemical Communications, Chemistry-A European Journal, Advanced Synthesis & Catalysis, Organic Chemistry Frontiers, The Journal of Organic Chemistry等上公开发表论文>50,其中以第一作者或通讯作者身份公开发表32篇论文,包含ESI高被引论文1H-index 15。已申请或授权的专利10项。

 

研究项目

主持国家自然科学基金项目一项江苏省自然科学基金项目一项。

 

教学

指导的本科生(郭一聪)获得2020届优秀本科毕业论文。

指导的研究生(谢婷)获得2020届优秀硕士毕业论文。

 

研究成果(仅列通讯或第一作者)

33. X.-Q. Chu (褚雪强),* D. Ge, Y.-Y. Cui, Z.-L. Shen,* C.-J. Li.* Desulfonylation via Radical Process: Recent Developments in Synthetic Applications. Chem. Rev. 2021, Under Revision. (Invited Review)

32. D. Ge, X. Wang, X.-Q. Chu (褚雪强),* Difluoroalkylation/1,2-Aryl Migration of Allylic Alcohols Under Transition Metal-Free Conditions. Tetrahedron Lett. 2021, DOI: 10.1016/j.tetlet.2021.153002.

31. D. Ge, X.-L. Luo, X. Tang, C.-B. Pang, X. Wang, X.-Q. Chu (褚雪强),* Metal-Free [3 + 2 + 1] Annulation of Allylic Alcohols, Ketones, and Ammonium Acetate: Radical-Involving Synthesis of 2,3-Diarylpyridine Derivatives. Org. Biomol. Chem. 2021, 19, 2277-2283. (This article is part of the themed collection: Synthetic methodology in OBC)

30. D.-Q. Wang,* C. Zhang, L.-W. Sun, X.-L. Luo, W. Rao, X. Wang, Z.-L. Shen, X.-Q. Chu (褚雪强),* Defluorinative Phosphorylation of Perfluoroalkyl Ketones: Synthesis of Fluoroalkylated and Phosphorylated Furan Derivatives. Org. Chem. Front. 2021, DOI: 10.1039/D0QO01631D.

29. S.-Z. Cai,# D. Ge,# L.-W. Sun, W. Rao, X. Wang, Z.-L. Shen,* X.-Q. Chu (褚雪强),* Three-Component Heteroannulation for Tetrasubstituted Furan Construction Enabled by Successive Defluorination and Dual Sulfonylation Relay. Green Chem. 2021, 23, 935–941.

28. B.-Q. Cheng, D. Ge,* X. Wang, X.-Q. Chu (褚雪强),* Perfluoroalkyl Halides as Fluorine-Containing Building Blocks for the Synthesis of Fluoroalkylated Heterocycles. Chin. J. Org. Chem. 2021, DOI: 10.6023/cjoc202009035. (In Chinese, Review)

27. X.-Q. Chu (褚雪强),* M.-L. Zhi, S.-X. Zhang, Y.-W. Wang, W. Rao, H. Xu, Z.-L. Shen,* Palladium-Catalyzed Defluorinative Alkynylation of Polyfluoroalkyl Ketones with Alkynes for the Synthesis of Fluorinated Fused Furans. Org. Chem. Front. 2021, 8, 572–578.

26. D. Ge, M.-L. Wang, X. Wang, X.-Q. Chu (褚雪强),* Iron-Catalyzed C-O Bond Functionalization of Butyrolactam Derivatives with Various N-/C-Nucleophiles. .

25. T. Xie, C. Zhang, S.-X. Zhang, W. Rao, H.-Y. Xu, Z.-L. Shen,* X.-Q. Chu (褚雪强),* Synthesis of Polycyclic Furan and Chromene Derivatives via Cascade Reactions Enabled by Cleavage of Multiple C(sp3)-F Bonds.

24. X.-Q. Chu (褚雪强),* T. Xie, Y.-W. Wang, X.-R. Li, W. Rao, H. Xu, Z.-L. Shen,* Synthesis of Di(hetero)aryl Sulfides by Defluorinative Sulfenylation of Polyfluoroalkyl Ketones with Sodium Sulfinates or Arylsulfonyl Chlorides. .

23. T. Xie,# G.-Q. Wang,# Y.-W. Wang, W. Rao, H. Xu, S. Li,* Z.-L. Shen,* X.-Q. Chu (褚雪强),* Selective Quadruple C(sp3)-F Functionalization of Polyfluoroalkyl Ketones. iScience 2020, 23, 101259.

22. S.-W. Zhao, S.-Z. Cai, M.-L. Wang, W. Rao, H. Xu, L. Zhang, X.-Q. Chu (褚雪强),* Z.-L. Shen,* Selective C(sp3)-H Functionalization of Alkyl Esters with N-/S-/O-Nucleophiles Using Perfluoroalkyl Iodide as Oxidant. Adv. Synth. Catal. 2020, 362, 3388–3394.

21. X.-Q. Chu (褚雪强), D. Ge, M.-L. Wang, W. Rao, T.-P. Loh,* Z.-L. Shen,* Chemo- and Regioselective Ring Construction Driven by Visible-Light Photoredox Catalysis: An Access to Fluoroalkylated Oxazolidines Featuring an All-Substituted Carbon Stereocenter. Adv. Synth. Catal. 2019, 361, 4082-4090.

20. X.-Q. Chu (褚雪强), Z.-L. Shen,* T.-P. Loh,* Regioselective (Hetero)aryl C-H Thianthrenation and Late-Stage Transformations. Chem 2019, 5, 1025-1027. (Preview).

19. X.-Q. Chu (褚雪强), D. Ge, T.-P. Loh,* Z.-L. Shen,* Oxidant-Directed Chemoselective Sulfonylation and Sulfonyloximation of Alkenes via Cleaving C-S Bond in TosMIC. Org. Chem. Front. 2019, 6, 835-840.

18. X.-Q. Chu (褚雪强), D. Ge, Z.-L. Shen,* T.-P. Loh,* Recent Advances in Radical-Initiated C(sp3)-H Bond Oxidative Functionalization of Alkyl Nitriles. ACS Catal. 2018, 8, 258−271 (Review, ACS Editors' Choice, Highly Cited Paper).

17. T. Xie, Y.-W. Zhang, L.-L. Liu, Z.-L. Shen, T.-P. Loh,* X.-Q. Chu (褚雪强).* Polycyclic Heteroaromatic Ring Construction Driven by Silver/Cobalt Co-Catalyzed Desulfonylative and Defluorinative Fragment-Recombination of Enol Nonaflates with Amidines. Chem. Commun. 2018, 54, 1272212725.

16. X.-Q. Chu (褚雪强), T. Xie, L. Li, D. Ge, Z.-L. Shen,* T.-P. Loh,* Combining Fluoroalkylation and Defluorination to Enable Formal [3 + 2 + 1] Heteroannulation by Using Visible-Light Photoredox Organocatalysis. Org. Lett. 2018, 20, 27492752.

15. X.-Q. Chu (褚雪强), B.-Q. Cheng, Y.-W. Zhang, D. Ge, Z.-L. Shen,* T.-P. Loh,* Copper-Catalyzed Three-Component Cyclization of Amidines, Styrenes, and Fluoroalkyl Halides for the Synthesis of Modular Fluoroalkylated Pyrimidines. Chem. Commun. 2018, 54, 26152618 (highlighted by X-MOL).

14. X.-Q. Chu (褚雪强), W.-B. Cao, X.-P. Xu,* S.-J. Ji,* Iron Catalysis for Modular Pyrimidine Synthesis through β-Ammoniation/Cyclization of Saturated Carbonyl Compounds with Amidines. J. Org. Chem. 2017, 82, 1145−1154.

13. X.-Q. Chu (褚雪强), X.-P. Xu,* S.-J. Ji,* TBAI-Catalyzed/Water-Assisted Double C−S Bond Formations: An Efficient Approach to Sulfides via Metal-Free Three-Component Reactions. Chem. Eur.J. 2016, 22, 14181–14185.

12. X.-Q. Chu (褚雪强), D. Liu, Z.-H. Xing, X.-P. Xu,* S.-J. Ji,* Palladium-Catalyzed Cyclization of Alkenes with Organohalides. Org. Lett. 2016, 18, 776 779.

11. X.-Q. Chu (褚雪强), Z.-H. Xing, H. Meng, X.-P. Xu,* S.-J. Ji,* Copper-Mediated Radical Alkylarylation of Unactivated Alkenes with Acetonitrile Leading to Fluorenes and Pyrroloindoles. Org. Chem. Front. 2016, 3, 165–169.

10. X.-Q. Chu (褚雪强), H. Meng, Y. Zi, X.-P. Xu,* S.-J. Ji,* Oxidative C(sp3)–H Functionalization of Acetonitrile and Alkanes with Allylic Alcohols under Metal-Free Conditions. Org. Chem. Front. 2015, 2, 216–220.

9. X.-Q. Chu (褚雪强), X.-P. Xu,* H. Meng, S.-J. Ji,* Synthesis of Functionalized Benzoxazines by Copper-Catalyzed C(sp3)–H Bond Functionalization of Acetonitrile with Olefinic Amides. RSC Adv. 2015, 5, 67829–67832.

8. X.-Q. Chu (褚雪强), H. Meng, X.-P. Xu,* S.-J. Ji,* One-Pot Synthesis of Allylic Sulfones, Ketosulfones, and Triflyl Allylic Alcohols from Domino Reactions of Allylic Alcohols with Sulfinic Acid under Metal-Free Conditions. Chem. Eur.J. 2015, 21, 11359–11368 (Front Cover & Hot Paper).

7. X.-Q. Chu (褚雪强), H. Meng, Y. Zi, X.-P. Xu,* S.-J. Ji,* Metal-Free Oxidative Radical Addition of Carbonyl Compounds to a, a-Diaryl Allylic Alcohols: Synthesis of Highly Functionalized Ketones. Chem. Eur.J. 2014, 20, 17198–17206.

6. X.-Q. Chu (褚雪强), Y. Zi, H. Meng, X.-P. Xu,* S.-J. Ji,* Synthesis of 1,4-Dihydroquinoline Derivatives under Transition-Metal-Free Conditions and Their Diverse Applications. Org. Biomol. Chem. 2014, 12, 4243–4251.

5. X.-Q. Chu (褚雪强), H. Meng, Y. Zi, X.-P. Xu,* S.-J. Ji,* Metal-Free Oxidative Direct C(sp3)–H Bond Functionalization of Ethers with a, a-Diaryl Allylic Alcohols. Chem. Commun. 2014, 50, 9718–9721.

4. X.-Q. Chu (褚雪强), Y. Zi, H. Meng, X.-P. Xu,* S.-J. Ji,* Radical Phosphinylation of a, a-Diaryl Allylic Alcohols with Concomitant 1,2-Aryl Migration. Chem. Commun. 2014, 50, 7642–7645.

3. X.-Q. Chu (褚雪强), Y. Zi, X.-M. Lu, S.-Y. Wang,* S.-J. Ji,* Intramolecular Pd-Catalyzed C-H Functionalization: Construction of Fused Tetracyclic Bis-Indole Alkaloid Analogues. Tetrahedron 2014, 70, 232–238.

2. X.-Q. Chu (褚雪强), S.-Y. Wang,* S.-J. Ji,* Recyclable NaHSO4 Catalyzed Alkylation of Tertenamides with Indoles or Amines in Water: Facile Construction of Pharmaceutically Analogous Bis-Alkaloid Scaffolds. RSC Adv. 2013, 3, 8380–8387.

1. X.-Q. Chu (褚雪强), R. Jiang, Y. Fang, Z.-Y. Gu, H. Meng, S.-Y. Wang,* S.-J. Ji,* Acidic-Functionalized Ionic Liquid as an Efficient, Green, and Metal-Free Catalyst for Benzylation of Sulfur, Nitrogen, and Carbon Nucleophiles to Benzylic Alcohols. Tetrahedron 2013, 69, 1166–1174.

专利

11. 褚雪强;沈志良;王雅文谢婷,一种三氟甲基取代嘧啶并[1,3]二氮杂䓬化合物及其制备方法,202011105476.3

10. 褚雪强;沈志良;支蔓玲一种2-氟烷基-3-炔基取代萘并呋喃化合物及其制备方法202010772271.4

9. 褚雪强;沈志良;赵世文一种多氟烯基取代的恶唑化合物及其制备方法,202010666373.8

8. 褚雪强;沈志良;蔡松州,一种氟烷基取代呋喃基双膦氧化合物及其制备方法,202010461262.3

7. 褚雪强;沈志良;蔡松州,一种氟烷基取代呋喃基单膦氧化合物及其制备方法,202010461540.5

6. 褚雪强;葛丹华;沈志良,一种硝基取代吲哚类化合物及其制备方法,201911065714.X

5. 褚雪强;沈志良;蔡松州,一种氟烷基取代呋喃类化合物及其制备方法201910797244.X

4. 褚雪强;沈志良;谢婷,一种多氟烷基取代苯并呋喃类化合物及其制备方法,201910387303.6

3. Shun-Jun Ji, Xue-Qiang Chu, Xiao-Ping Xu, Wenbin Cao, METHOD FOR SYNTHESIZING DISSYMMETRIC SULFOETHER, US 20180201576A1.

2. 纪顺俊;褚雪强;徐小平;曹文斌,一种非对称硫醚的合成方法,CN201610423506.2

1. 纪顺俊;褚雪强;徐小平,一种多取代嘧啶的制备方法,CN201610919655.8

 

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