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曲剑萍
阅读次数: 添加时间:2018/12/04 发布:管理员


个人简介


2016年至今      欧宝体育官方登录入口,先进化学制造研究院,教授

2011-2015        海德堡大学化学系,博士后,洪堡学者 (Günter Helmchen 教授)

2006-2011       上海有机化学研究所理学博士 (唐勇 研究员)

2001-2005       山东师范大学化学系,理学学士



研究方向


1. 新型过渡金属催化剂的设计以及在新反应开发配位聚合反应中的应用

2. 新型功能聚合物的合成方法以及应用开发;

3.手性聚酯聚酰胺聚砜等光学活性聚合物的研究



代表性论文


1. Copper-catalyzed oxidative benzylic C-H cyclization via iminyl radical from intermolecular anion-radical redox relay, X.-H. Shan, H.-X. Zheng, B. Yang, L. Tie, Jia-Le Fu, J.-P. Qu*, Y.-B. Kang,* Nature Commun. 2019, 10, 908.

2. Organocatalyzed Aerobic Oxidation of Aldehydes to Acids, P.-F. Dai, J.-P. Qu*, Y.-B. Kang,* Org. Lett. DOI: 10.1021/acs.orglett.9b00101  

3. Iridium-Catalyzed Asymmetric Allylic Substitution Reactions, Q. Cheng, H.-F. Tu, C. Zheng, J.-P. Qu, G. Helmchen,* Shu-Li You,* Chem. Rev. 2019, 119, 1855.

4. One-pot one-base conditions for two shots: organocatalyzed tandem isomerization-olefination of allylic alcohols, H.-X. Zheng, Qu, J.-P. Qu*, Y.-B. Kang,* Org. Chem. Front. 2018, 5, 2349.

5. Phenanthroline-tBuOK Promoted Intramolecular C–H Arylation of Indoles with ArI under Transition-Metal-Free Conditions, X.-H. Shan, B. Yang, H.-X. Zheng, Qu, J.-P. Qu*, Y.-B. Kang,* Org. Lett. 2018, 20, 7898.

6. Strategy for Overcoming Full Reversibility of Intermolecular Radical Addition to Aldehydes: Tandem C-H and C-O Bonds Cleaving Cyclization of (Phenoxymethyl)arenes with Carbonyls to Benzofurans, H.-X. Zheng, X.-H. Shan, J.-P. Qu*, Y.-B. Kang,* Org. Lett. 2018, 20, 3310.

7. Synthesis of Functionalized Indoles via Palladium-Catalyzed Aerobic Cycloisomerization of o-Allylanilines Using Organic Redox Cocatalyst, X.-S. Ning, M.-M. Wang, Qu, J.-P. Qu*, Y.-B. Kang,* J. Org. Chem.  2018, 83, 13523.

8. Tuning Regioselectivity of Wacker Oxidation in One Catalytic System: Small Change Makes Big Step, K.-F. Hu, X.-S. Ning, J.-P. Qu*, Y.-B. Kang,* J. Org. Chem. 2018, 83, 11327.

9. Pd-tBuONO Cocatalyzed Aerobic Indole Synthesis, X.-S. Ning, X. Liang, K.-F. Hu, C.-Z. Yao, J.-P. Qu*, Y.-B. Kang,* Adv. Synth. Catal. 2018, 360, 1590.

10. nBu4NOTf-Promoted Radical Self-Hydrogen Transferring Isomerization under Transition Metal-Free Conditions  H.-X. Zheng, C.-Z. Yao, J.-P. Qu*, Y.-B. Kang,* Org. Chem. Front. 2018, 5, 1213. 

11. Synthesis of Highly Functionalized Indoles and Indolones via Selectivity-Switchable Olefinations, T.-H. Ding, Z.-F. Xiao, J.-P. Qu*, Y.-B. Kang*, J. Org. Chem. 2018, 83, 2467.

12. Direct Wittig Olefination of Alcohols, Q.-Q. Li, Z. Shah, J.-P. Qu*, Y.-B. Kang*, J. Org. Chem. 2018, 83, 296. 

13. Applications of Iridium-Catalyzed Asymmetric Allylic Substitution Reactions in Target-Oriented Synthesis, J.-P. Qu, G. Helmchen*, Acc. Chem. Res. 2017, 50, 2539. 

14. Dehydrogenative Synthesis of Linear α,β-Unsaturated Aldehydes with Oxygen at Room Temperature Enabled by tBuONO,  M.-M. Wang, X.-S. Ning J.-P. Qu*, Y.-B. Kang*, ACS Catal. 2017, 7, 4000. 

15. Organopromoted Selectivity-Switchable Synthesis of Polyketones, J. Liu, K.-F. Hu, J.-P. Qu*, Y.-B. Kang*, Org. Lett. 2017, 19, 5593. 

16. H.-X. Zheng, X.-H. Shan, J.-P. Qu*, Y.-B. Kang*, Transition-Metal-Free Hydrogenation of Aryl Halides: From Alcohol to Aldehyde, Org. Lett. 2017, 19, 5114. 

Selected Post-Doctoral and Ph.D. Publications 

1. Enantio- and Regioselective Iridium-Catalyzed Allylic Esterification, J.-P. Qu, L. Roeberg, G. Helmchen*, J. Am. Chem. Soc. 2014, 136, 1272. 

2. Highly Enantioselective [3+2] Annulation of Cyclic Enol Silyl Ethers with Donor–Acceptor Cyclopropanes: Accessing 3a-Hydroxy [n.3.0] Carbobicycles,Xu, J.-P. Qu, S. Liao, H. Xiong, Y. Tang*, Angew. Chem. Int. Ed. 2013, 52, 4004. 

3. Highly Diastereoselective Construction of Fused Carbocycles from Cyclopropane-1,1-dicarboxylates and Cyclic Enol Silyl Ethers: Scope, Mechanism, and Origin of Diastereoselectivity,J.-P. Qu, Y. Liang, H. Xu, X. Sun, Z. Yu, Y. Tang*, Chem. Eur. J. 2012, 18, 2196. 

4. Switchable Reactions of Cyclopropanes with Enol Silyl Ethers. Controllable Synthesis of Cyclopentanes and 1,6-Dicarbonyl Compounds,J.-P. Qu, C. Deng, J. Zhou, X. Sun, Y. Tang*, J. Org. Chem. 2009, 74, 7684. 

5. Ligand-accelerated Asymmetric [1,2]-Stevens Rearrangment of Sufur Ylides via Decomposition of Diazomalonates Catalyzed by Chiral Bisoxazoline/Copper Complex,J.-P. Qu, Z. Xu, J. Zhou, C. Cao, X. Sun, L. Dai, Y. Tang*, Adv. Synth. Catal. 2009, 351, 308.



曲剑萍 教授

Email:ias_jpqu@njtech.edu.cn





地址:南京浦口区浦珠南路30号 邮编:211880 电话:025-58139535、9536、9537 邮箱:chem@njtech.edu.cn

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